Di-μ1,1-azido-bis[azido(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]

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Di-μ1,1-azido-bis­[azido­(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]

In the title azide-bridged dinuclear centrosymmetric nickel(II) complex, [Ni(2)(N(3))(4)(C(12)H(12)N(2))(2)], the Ni(II) atom is five-coordinated by two N atoms of the 5,5'-dimethyl-2,2'-bipyridine ligand and three N atoms from three azide ligands in a distorted trigonal-bipyramidal geometry. The Ni⋯Ni distance is 3.2398 (12) Å.

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Di-μ-azido-di­azidodi-μ-oxalato-di­histamine­tetra­copper(II) 0.9-hydrate

The title compound, [Cu4(C2O4)2(N3)4(C5H9N3)2]·0.9H2O, contains a tetranuclear Cu(II)-based molecule composed of two oxalate-bridged Cu(II) dimers linked through end-on azide ions and related by an inversion center. The tetranuclear unit contains two crystallographically independent Cu(II) ions. One Cu(II) ion coordinates to two N atoms of a histamine mol-ecule, two O atoms of a bridging oxalat...

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Poly[di-μ3-azido-μ2-4,4′-bipyridine-dicopper(I)]

In the crystal structure of the title compound, [Cu(2)(N(3))(2)(C(10)H(8)N(2))](n), each Cu(I) atom is coordinated by two symmetry-related azide anions and 4,4'-bipyridine (bipy) ligands in a strongly distorted tetra-hedral geometry. The Cu atom and the azide anion occupy general positions while the bipy mol-ecule is located on a centre of inversion. Each two symmetry-related copper(I) cations ...

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catena-Poly[[(1,10-phenanthroline)cobalt(II)]-di-μ-azido]

In the crystal structure of the binuclear title complex, [Co(N(3))(2)(C(12)H(8)N(2))](n), each Co(II) cation is coordinated by two N atoms from one chelating 1,10-phenanthroline ligand and four azide ligands in a slightly distorted octa-hedral coordination. The two Co(II) cations of the binuclear complex are related by an inversion centre and are bridged by two symmetry-related azide ligands in...

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catena-Poly[di-μ1,1-azido-(1,10-phenanthroline)cadmium(II)]

The asymmetric unit of the title Cd(II) compound, [Cd(N(3))(2)(C(12)H(8)N(2))](n), contains a Cd(II) atom, located on a twofold axis passing through the middle of the phenanthroline mol-ecule, one azide ion and half of a 1,10-phenanthroline mol-ecule. The Cd(II) atom exhibits a distorted octa-hedral coordin-ation including one chelating 1,10-phenanthroline ligand and four azide ligands. The cry...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808037902